INTERACTION OF COMPONENTS IN THE La-Li-Ni-Si SYSTEM AT A TEMPERATURE OF 400ºС

Authors

DOI:

https://doi.org/10.30888/2663-5712.2024-24-00-004

Keywords:

Lanthanum, Lithium, Nickel, Silicon, quaternary system, phase equilibria, synthesis, crystal structure, solid solution.

Abstract

The interaction of the components in the La Li Ni Si system in the LaSi LiSi Ni Si region was investigated by X-ray phase, local X-ray spectral analyses and microstructural analysis methods at 400ºC. The alloys were prepared by arc melting of stoichiomet

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References

Павлюк В.В., Бодак О.І., Кеворков Д.Г., Печарський В.К. Дослідження твердих розчинів LaLixCu2-xSi2 та LaLixCu2-xGe2 в системах {La, Ce}-Li-Cu-{Si, Ge} при 470 К // Доп. АН України. – 1993. 9. 87-89.

Матвіїшин Р.І. Взаємодія Ербію із перехідними металами (Co, Ni), Літієм та р-елементами IV групи (Si, Ge):Автореф. дис. канд. хім. наук. Львів, 2009.

Стецьків А. Взаємодія компонентів у потрійній системі La–Lі–Sі за температури 400 ºC // Вісник Львівського університету. Серія хімічна. – 2017. – Випуск 58. Частина 1. –С. 21–26.

Langer T., Dupke S., Eckert H., Matar S.F. 7Li and 29Si solid state NMR and chemical bonding of La2Li2Si3 // Solid State Sciences. – 2012. – Vol. 14, Is. 3. – P. 367-374.

Merlo F., Palenzona A., Pani M., Dhar S.K., Kulkarni R. Structural and magnetic properties of the new R2Li2Si3compounds (R = La, Ce, Pr, Nd, Sm) // Journal of Alloys and Compounds. – 2005. – Vol. 394, Issues 1–2. – P. 101-106.

Zhou H., Yao Q., Yuan S., Liu J., Deng H.Phase relationships in the La–Ni–Si system at 673 K // Journal of Alloys and Compounds. – 2004. – Vol. 366. – P. 161–164.

Lee W.H., Yang F.A., Shih C.R., Yang H.D. Crystal structure and superconductivity in the Ni-based ternary compound LaNiSi // Phys. Rev. B: Condens. Matter. – 1994. – Vol. 50. – P. 6523-6525.

Гладишевський Є.І., Бодак О.І. Сполуки із структурою типу AlB2 в системі Ce-Ni-Si і в споріднених системах // Доп. АН УРСР. Cер. Б. – 1965. – № 4. – С. 601-604.

Prots' Y.M., Jeitschko W. Lanthanum Nickel Silicides with the General Formula La(n+1)(n+2)Nin(n-1)+2Sin(n+1) and Other Series of Hexagonal Structures with Metal: Metalloid Ratios Close to 2:1 // Inorg. Chem. – 1998. – Vol. 37. – P. 5431-5438.

Morozkin A.V., Seropegin Yu.D., Gribanov A.V., Sviridov I.A., Kurenbaeva J.M. Analysis of the melting temperatures of RTX2 (CeNiSi2structure) and RT2X2 (CeGa2Al2 structure) compounds [R=La,Ce,Sm,Er,Tm; T=Fe,Co,Ni; X=Si,Ge] // J. Alloys Compd. – 1998. – Vol. 264. – P. 190-196.

Бодак О.І., Гладишевський Є.І. Кристалічна структура сполуки CeNi8.6Si2.4 і споріднених до неї сполук // Доп. АН УРСР. Cер. А. – 1969. – № 5. – С. 452-455.

Krypyakevych P.I., Zaretschniuk O.S., Gladyshevskii E.I., Bodak O.I. Ternäre Verbindungen vom NaZn13-Typ // Z. Anorg. Allg. Chem. – 1968. – Bd. 58. – S. 90-96.

Bodak O.I., Gladyshevskii E.I., Mis'kiv M.G., Bodak O.I. Crystal structure of Ce2NiSi and related compounds // Sov. Phys. Crystallogr. – 1972. – Vol. 17. – P. 439-441.

Gout D., Benbow E., Miller G.J., Gout D. Structure and bonding consequences in the pseudo-binary system Ln5Si3-xMx (Ln= La, Ce or Nd; M= Ni or Co) // J. Alloys Compd. – 2002. – Vol. 338. – P. 153-164.

Bodak O.I., Gladyshevskii E.I., Kharchenko O.I. Crystal structures of Ce6Ni2Si3 and related compounds // Sov. Phys. Crystallogr. – 1974. – Vol. 19. – P. 45-46.

Michor H., Bauer E., El-Hagary M., Dusek C.Kondo-lattice behaviour of CeNi9Si4 // Physica B: Condensed Matter. – 2003. – Vol. 329-333. – P. 572-573.

Pani M., Manfrinetti P., Provino A., Fang Yuan, Mozharivskyj Y., Morozkin A.V., Knotko A.V., Garshev A.V. New tetragonal derivatives of cubic NaZn13-type structure: RNi6Si6 compounds, crystal structure and magnetic ordering (R=Y,La,Ce,Sm,Gd–Yb) // J. Solid State Chemistry. – 2013. – Vol. 210. – P. 45-52.

Merlo F., Fornasini M.L., Pani M. On the existence and the crystal structure of novel R3TSi3 intermetallic phases (R= rare earths; T= Fe, Co, Ni) // J. Alloys Compd. – 2005. – Vol. 387. – P. 165-171.

Fritsch V., Bobev S., Thompson J.D., Sarrao J.L. Antiferromagnetic order in Ce3Ni2+xSi8-x (x≈ 1) // J. Alloys Compd. – 2005. – Vol. 388. – P. 28-33.

Fujii H. Structure and superconductivity of the ternary intermetallics of La3Ni4Si4, La3Ni4Ge4, and La3Pd4Si4 // J. Phys.: Condens. Matter. – 2006. – Vol. 18. – P. 8037-8047.

Morozkin A.V., Knotko A.V., Yapaskurt V.O., Yuan F., Mozharivskyj Y.A., Nirmala R. New orthorhombic derivative of CaCu5-type structure: RNi4Si compounds (R= Y, La, Ce, Sm, Gd-Ho), crystal structure and some magnetic properties // J. Solid State Chem. – 2013. – Vol. 208. – P. 9-13.

Liang J.K., J.T. Zhao The influenca of Si on phase relation and hydrogen absorbtion properties of LaNi5 // Chin. Phys. – 1987. – Vol. 7. – P. 29-34.

Schwarzenbach D. Program LATCON: refine lattice parameters. Lausanne: University of Lausanne, 1966.

Kraus W., Nolze G. PowderCell for Windows. Berlin: Federal Institute for Materials Research and Testing, 1999.

Akselrud L. G., Grin Yu. N. WinCSD: software package for crystallographic calculations (Version 4) // J. Fppl Crystallogr. 2014. Vol. 47. P. 803–805.

Rodriguez-Carvajal J. FULLPROF: A Program for Rietveld Refinement and Pattern Matching Analysis, version 3.5d; Laboratoire Léon Brillouin (CEA–CNRS): Saclay, France, 1998.

Published

2024-03-30

How to Cite

Стецьків, А., & Гаврищук, Л. (2024). INTERACTION OF COMPONENTS IN THE La-Li-Ni-Si SYSTEM AT A TEMPERATURE OF 400ºС. SWorldJournal, 2(24-02), 60–67. https://doi.org/10.30888/2663-5712.2024-24-00-004

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